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Efficient Concentration of PB From Water by Reactions With Layered Alkali Silicates, Magadiite and Octosilicate

Published online by Cambridge University Press:  01 January 2024

Donhatai Sruamsiri ,
Thipwipa Sirinakorn  and
Makoto Ogawa Open the ORCID record for Makoto Ogawa [Opens in a new window]
Donhatai Sruamsiri
Affiliation:
School of Energy Science and Engineering, Vidyasirimedhi Institute of Science and Technology (VISTEC), 555 Moo 1 Payupnai, Wangchan, Rayong, 21210, Thailand
Thipwipa Sirinakorn
Affiliation:
School of Molecular Science and Engineering, Vidyasirimedhi Institute of Science and Technology (VISTEC), 555 Moo 1 Payupnai, Wangchan, Rayong, 21210, Thailand
Makoto Ogawa*
Affiliation:
School of Energy Science and Engineering, Vidyasirimedhi Institute of Science and Technology (VISTEC), 555 Moo 1 Payupnai, Wangchan, Rayong, 21210, Thailand
*
*E-mail address of corresponding author: waseda.ogawa@gmail.com
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Abstract

Human health problems are often related to contamination of the aqueous environment by toxic metal ions. In the present study, two layered alkali silicates (magadiite and octosilicate) were examined to assess removal of Pb2+ from aqueous solutions in terms of quantity and kinetics. The ion-exchange reaction between the silicates and aqueous solutions of lead(II) acetate at various concentrations was examined at room temperature for 24 h. The adsorption isotherms were H-type, showing the strong interactions between Pb2+ and the silicates. The amounts of Pb2+ adsorbed were as much as 1.23 mmol Pb/g magadiite and 2.32 mmol Pb/g octosilicate, which are larger than the reported values for various ion exchangers. They were larger than the theoretical cation exchange capacities (2.2 and 3.7 meq/g for magadiite and octosilicate, respectively), suggesting that the collection of Pb2+ included the precipitation as basic lead salts in addition to the ion exchange. The adsorption isotherms for magadiite and octosilicate fitted the Langmuir equation with correlation coefficients, R2, of 0.9991 and 0.9972, respectively. The adsorption of Pb2+ onto the layered alkali silicates from acidic aqueous solution was examined to obtain smaller amounts of adsorbed Pb2+ (0.32 mmol Pb/g magadiite and 0.34 mmol Pb/g octosilicate), confirming the important role of pH on the surface charge of the layered silicates in terms of ion exchange. The adsorption of Pb2+ reached equilibrium within 5 min for magadiite while it took 60 min for octosilicate. The difference was in the particle morphology; smoother diffusion of Pb2+ was possible through flower-shaped aggregates of particles of magadiite.

Keywords

Layered alkali silicateMagadiiteOctosilicatePb2+ collectionWater purification
Type
Article
Information
Clays and Clay Minerals , Volume 69 , Issue 4 , August 2021 , pp. 416 - 424
Copyright
Copyright © Clay Minerals Society 2021

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Footnotes

This paper is based on a presentation made during the 4th Asian Clay Conference, Thailand, June 2020.

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